Rust Veto As 2h2q5u
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MATERIAL SAFETY DATA SHEET Issuing Date: 21-Nov-2011
Revision Date: 21-Nov-2011
Version 2
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Rust Veto AS
1.1. Product identifier
Rust Veto AS is a grease-type rust preventive containing high quality corrosion inhibitors and formulated for use in Rust-Veto AS Product Name extremes of climatic conditions. It may be 1.2. Relevant identified uses of the substance or mixture and uses advised against applied readily by stiff brush at -30°C but when in place it sets to a soft greasy film Rust preventative, Use as Directed. Recommended use which will not melt or run off at temperatures up to 120°C. Rust Veto AS was Any other purpose. Uses advised against particularly designed for the long-term protection of threads on offshore tubular 1.3. Details of the supplier of the safety data sheet goods, stored in hostile outdoor Manufacturer, Importer, Supplier environments. Houghton plc Rust Veto AS is designed specifically for Beacon Road long-term protection of drill pipe and Trafford Park capped casing threads, especially in Manchester M17 1AF offshore tubular products. It protects metal Tel: +44 (0)161 874 5000 against corrosion for up to 12 months during outdoor storage in extreme climate [email protected] E-mail Address conditions. Indoors, it provides protection 1.4. Emergency telephone number for two years or more. Rust Veto can be removed easily when required, and it does +44 (0) 161 874 5000 (9 - 5) Emergency telephone not interfere with subsequent manufacturing processes. Product Code(s)
67817
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture According to present data no classification and labelling is required according to Directives 67/548/EEC or 1999/45/EC.
2.2. Label Elements Symbol(s) Not dangerous
R-phrase(s) None S-phrase(s) None
_____________________________________________________________________________________________ Page 1 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ 2.3. Other hazards None
3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Non-hazardous ingredients
For the full text of the R-phrases mentioned in this Section, see Section 16 For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES 4.1. Description of first-aid measures General advice
If symptoms persist, call a physician.
Inhalation
Move to fresh air.
Skin
Wash off immediately with soap and plenty of water, Wash contaminated clothing before reuse.
Eye
Rinse thoroughly with water as necessary; Keep eye wide open while rinsing.
Ingestion
Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting without medical advice.
Protection of First-aiders
Use personal protective equipment
4.2. Most important symptoms and effects, both acute and delayed Main Symptoms
None
4.3. Indication of immediate medical attention and special treatment needed Notes to physician
Treat symptomatically
5. FIRE-FIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment: Water spray, dry chemical, carbon dioxide (CO2), or foam Extinguishing media which shall not be used for safety reasons None 5.2. Special hazards arising from the substance or mixture Special Hazard Thermal decomposition can lead to release of irritating gases and vapors.
_____________________________________________________________________________________________ Page 2 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ Hazardous Decomposition Products Incomplete combustion and thermolysis produces potentially toxic gases such as carbon monoxide and carbon dioxide. 5.3. Advice for fire-fighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear
6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Advice for non-emergency personnel
Material can create slippery conditions
Advice for emergency responders
For personal protection see section 8
6.2. Environmental precautions Prevent further leakage or spillage if safe to do so 6.3. Methods and materials for containment and cleaning up Sweep up and shovel into suitable containers for disposal. 6.4. Reference to other sections See Section 8/12/13 for additional information
7. HANDLING AND STORAGE 7.1. Precautions for safe handling Ensure adequate ventilation. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep container tightly closed in a dry and well-ventilated place Incompatible Materials Strong oxidizing agents, Strong acids, Strong bases 7.3. Specific end uses Specific use(s)
Rust preventative, Use as Directed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Contains no substances with occupational exposure limit values
_____________________________________________________________________________________________ Page 3 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________
Derived No Effect Level (DNEL)
No information available
Predicted No Effect Concentration (PNEC)
No information available
8.2. Exposure controls Ensure adequate ventilation, especially in confined areas
Engineering Measures
Personal protective equipment Tightly fitting safety goggles Protective gloves. Barrier cream. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Long sleeved clothing No special protective equipment required In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit
Eye Protection Hand Protection
Skin and body protection Respiratory protection
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice.
Environmental Exposure Controls Thermal hazards
No special environmental precautions required None under normal use conditions
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state @20°C Odor Property pH Melting/freezing point Boiling point/boiling range Flash Point Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit
Paste/Gel Mild Values Not applicable . > 150 °C > 300 °C > 200 °C No information available No information available
Appearance Odor Threshold
brown Not applicable Note
Cleveland Open Cup (COC) negligible
No information available No information available
. Vapor pressure No information available Vapor density 0.90 Relative density Immiscible in water Water Solubility No information available Solubility in other solvents Partition coefficient: n-octanol/water Not applicable No information available Autoignition temperature No information available Decomposition temperature No information available. Viscosity (kinematic) Not applicable Explosive properties Not applicable Oxidizing Properties
negligible @15.5C
Other information
_____________________________________________________________________________________________ Page 4 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ VOC Content
No information available
10. STABILITY AND REACTIVITY 10.1. Reactivity None under normal use conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None under normal use conditions 10.4. Conditions to avoid Do not freeze 10.5. Incompatible Materials Strong oxidizing agents, Strong acids, Strong bases 10.6. Hazardous decomposition products Incomplete combustion and thermolysis produces potentially toxic gases such as carbon monoxide and carbon dioxide.
11. TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Product Information - Principle Routes of Exposure Inhalation
No known hazard by inhalation; LC50>5mg/l/4h (rat)
Eye
None known
Skin
No known hazard in with skin; LD50>2000 mg/kg (rat)
Ingestion
None known; LD50>2000 mg/kg (rat)
Acute toxicity - Product Information Product does not present an acute toxicity hazard based on known or supplied information.
Acute toxicity - Component Information Non-hazardous ingredients
Irritation
May cause irritation.
_____________________________________________________________________________________________ Page 5 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ Corrosivity
None.
Sensitization
None known
Repeated Dose Toxicity
None known
Carcinogenicity
None known
Mutagenicity
None known
Toxicity to Reproduction
None known
12. ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity effects
Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants
12.2. Persistence and degradability Not readily biodegradable. 12.3. Bioaccumulative potential Product has a low potential to bioconcentrate
12.4. Mobility in soil The product is insoluble and floats on water 12.5. Results of PBT and vPvB assessment No information available 12.6. Other adverse effects None known
13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste from Residues / Unused Products
Dispose of in accordance with local regulations
Special risks and unsuitable means None when handling product waste/waste packaging Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal
_____________________________________________________________________________________________ Page 6 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ Other information
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the based on the application for which the product was used.
14. TRANSPORT INFORMATION 14.1. UN-Number Not regulated 14.2. UN proper shipping name Not regulated 14.3. Transport hazard class Not regulated 14.4. Packing group Not regulated 14.5. Environmental Hazards None 14.6. Special precautions for s None 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable IMDG/IMO
Not regulated
ADR/RID
Not regulated
ICAO/IATA
Not regulated
15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Take note of Dir 94/33/EC on the protection of young people at work.
_____________________________________________________________________________________________ Page 7 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 & (EC) No. 1272/2008 & (EC) 1999/45. Acts of Parliament: The Health and Safety at Work etc. Act 1974. Environment Protection Act 1990 Statutory Instruments: Control of Substances Hazardous to Health Regulations 2002. Chemicals (Hazard Information and Packaging) Regulations 2009 The Carriage of Dangerous Goods Regulations 2009 The Hazardous Waste (England and Wales) Regulations 2005 Workplace exposure limits (EH40) The classification detailed on this Safety Data Sheet refer to the neat material only. Dilution of the product may reduce the classification
15.2. Chemical Safety Assessment No information available
16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 No information available Full text of H-Statements referred to under section 2 and 3 No information available Exposure scenario No information available Issuing Date:
21-Nov-2011
Revision Date:
21-Nov-2011
Revision Note
Not applicable
Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
_____________________________________________________________________________________________ Page 8 / 8
Revision Date: 21-Nov-2011
Version 2
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Rust Veto AS
1.1. Product identifier
Rust Veto AS is a grease-type rust preventive containing high quality corrosion inhibitors and formulated for use in Rust-Veto AS Product Name extremes of climatic conditions. It may be 1.2. Relevant identified uses of the substance or mixture and uses advised against applied readily by stiff brush at -30°C but when in place it sets to a soft greasy film Rust preventative, Use as Directed. Recommended use which will not melt or run off at temperatures up to 120°C. Rust Veto AS was Any other purpose. Uses advised against particularly designed for the long-term protection of threads on offshore tubular 1.3. Details of the supplier of the safety data sheet goods, stored in hostile outdoor Manufacturer, Importer, Supplier environments. Houghton plc Rust Veto AS is designed specifically for Beacon Road long-term protection of drill pipe and Trafford Park capped casing threads, especially in Manchester M17 1AF offshore tubular products. It protects metal Tel: +44 (0)161 874 5000 against corrosion for up to 12 months during outdoor storage in extreme climate [email protected] E-mail Address conditions. Indoors, it provides protection 1.4. Emergency telephone number for two years or more. Rust Veto can be removed easily when required, and it does +44 (0) 161 874 5000 (9 - 5) Emergency telephone not interfere with subsequent manufacturing processes. Product Code(s)
67817
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture According to present data no classification and labelling is required according to Directives 67/548/EEC or 1999/45/EC.
2.2. Label Elements Symbol(s) Not dangerous
R-phrase(s) None S-phrase(s) None
_____________________________________________________________________________________________ Page 1 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ 2.3. Other hazards None
3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Non-hazardous ingredients
For the full text of the R-phrases mentioned in this Section, see Section 16 For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES 4.1. Description of first-aid measures General advice
If symptoms persist, call a physician.
Inhalation
Move to fresh air.
Skin
Wash off immediately with soap and plenty of water, Wash contaminated clothing before reuse.
Eye
Rinse thoroughly with water as necessary; Keep eye wide open while rinsing.
Ingestion
Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting without medical advice.
Protection of First-aiders
Use personal protective equipment
4.2. Most important symptoms and effects, both acute and delayed Main Symptoms
None
4.3. Indication of immediate medical attention and special treatment needed Notes to physician
Treat symptomatically
5. FIRE-FIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment: Water spray, dry chemical, carbon dioxide (CO2), or foam Extinguishing media which shall not be used for safety reasons None 5.2. Special hazards arising from the substance or mixture Special Hazard Thermal decomposition can lead to release of irritating gases and vapors.
_____________________________________________________________________________________________ Page 2 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ Hazardous Decomposition Products Incomplete combustion and thermolysis produces potentially toxic gases such as carbon monoxide and carbon dioxide. 5.3. Advice for fire-fighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear
6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Advice for non-emergency personnel
Material can create slippery conditions
Advice for emergency responders
For personal protection see section 8
6.2. Environmental precautions Prevent further leakage or spillage if safe to do so 6.3. Methods and materials for containment and cleaning up Sweep up and shovel into suitable containers for disposal. 6.4. Reference to other sections See Section 8/12/13 for additional information
7. HANDLING AND STORAGE 7.1. Precautions for safe handling Ensure adequate ventilation. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures/Storage conditions Keep container tightly closed in a dry and well-ventilated place Incompatible Materials Strong oxidizing agents, Strong acids, Strong bases 7.3. Specific end uses Specific use(s)
Rust preventative, Use as Directed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Contains no substances with occupational exposure limit values
_____________________________________________________________________________________________ Page 3 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________
Derived No Effect Level (DNEL)
No information available
Predicted No Effect Concentration (PNEC)
No information available
8.2. Exposure controls Ensure adequate ventilation, especially in confined areas
Engineering Measures
Personal protective equipment Tightly fitting safety goggles Protective gloves. Barrier cream. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Long sleeved clothing No special protective equipment required In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit
Eye Protection Hand Protection
Skin and body protection Respiratory protection
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice.
Environmental Exposure Controls Thermal hazards
No special environmental precautions required None under normal use conditions
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state @20°C Odor Property pH Melting/freezing point Boiling point/boiling range Flash Point Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit
Paste/Gel Mild Values Not applicable . > 150 °C > 300 °C > 200 °C No information available No information available
Appearance Odor Threshold
brown Not applicable Note
Cleveland Open Cup (COC) negligible
No information available No information available
. Vapor pressure No information available Vapor density 0.90 Relative density Immiscible in water Water Solubility No information available Solubility in other solvents Partition coefficient: n-octanol/water Not applicable No information available Autoignition temperature No information available Decomposition temperature No information available. Viscosity (kinematic) Not applicable Explosive properties Not applicable Oxidizing Properties
negligible @15.5C
Other information
_____________________________________________________________________________________________ Page 4 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ VOC Content
No information available
10. STABILITY AND REACTIVITY 10.1. Reactivity None under normal use conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None under normal use conditions 10.4. Conditions to avoid Do not freeze 10.5. Incompatible Materials Strong oxidizing agents, Strong acids, Strong bases 10.6. Hazardous decomposition products Incomplete combustion and thermolysis produces potentially toxic gases such as carbon monoxide and carbon dioxide.
11. TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Product Information - Principle Routes of Exposure Inhalation
No known hazard by inhalation; LC50>5mg/l/4h (rat)
Eye
None known
Skin
No known hazard in with skin; LD50>2000 mg/kg (rat)
Ingestion
None known; LD50>2000 mg/kg (rat)
Acute toxicity - Product Information Product does not present an acute toxicity hazard based on known or supplied information.
Acute toxicity - Component Information Non-hazardous ingredients
Irritation
May cause irritation.
_____________________________________________________________________________________________ Page 5 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ Corrosivity
None.
Sensitization
None known
Repeated Dose Toxicity
None known
Carcinogenicity
None known
Mutagenicity
None known
Toxicity to Reproduction
None known
12. ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity effects
Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants
12.2. Persistence and degradability Not readily biodegradable. 12.3. Bioaccumulative potential Product has a low potential to bioconcentrate
12.4. Mobility in soil The product is insoluble and floats on water 12.5. Results of PBT and vPvB assessment No information available 12.6. Other adverse effects None known
13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste from Residues / Unused Products
Dispose of in accordance with local regulations
Special risks and unsuitable means None when handling product waste/waste packaging Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal
_____________________________________________________________________________________________ Page 6 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ Other information
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the based on the application for which the product was used.
14. TRANSPORT INFORMATION 14.1. UN-Number Not regulated 14.2. UN proper shipping name Not regulated 14.3. Transport hazard class Not regulated 14.4. Packing group Not regulated 14.5. Environmental Hazards None 14.6. Special precautions for s None 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable IMDG/IMO
Not regulated
ADR/RID
Not regulated
ICAO/IATA
Not regulated
15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Take note of Dir 94/33/EC on the protection of young people at work.
_____________________________________________________________________________________________ Page 7 / 8
67817 - Rust-Veto AS Revision Date: 21-Nov-2011 _____________________________________________________________________________________________ This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 & (EC) No. 1272/2008 & (EC) 1999/45. Acts of Parliament: The Health and Safety at Work etc. Act 1974. Environment Protection Act 1990 Statutory Instruments: Control of Substances Hazardous to Health Regulations 2002. Chemicals (Hazard Information and Packaging) Regulations 2009 The Carriage of Dangerous Goods Regulations 2009 The Hazardous Waste (England and Wales) Regulations 2005 Workplace exposure limits (EH40) The classification detailed on this Safety Data Sheet refer to the neat material only. Dilution of the product may reduce the classification
15.2. Chemical Safety Assessment No information available
16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 No information available Full text of H-Statements referred to under section 2 and 3 No information available Exposure scenario No information available Issuing Date:
21-Nov-2011
Revision Date:
21-Nov-2011
Revision Note
Not applicable
Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
_____________________________________________________________________________________________ Page 8 / 8
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